Only after his mother's death (1715), he came to Portugal. While he lived in Spain, King Charles II granted him the title of Duke of Baños, and he served in the Spanish army, both in the Catalonia and in the Flanders campaigns.
He died single without issue.
After his death the Duchy was claimed by his nephew, António de Lencastre Ponce de León (son of Joaquin 7th Duke of Los Arcos), and by José de Mascarenhas, 8th Count of Santa Cruz and 5th Marquis of Gouveia (descending from Álvaro and Juliana of Lencastre through female line).